Strategies to quench quantum tunneling of magnetization in lanthanide single molecule magnets
Abinash Swain, Tanu Sharma, Gopalan Rajaraman
Abstract
CASSCF/RASSI-SO methods have played a prominent role in estimating various spin Hamiltonian parameters and establishing the mechanism of magnetization relaxation in this class of molecules. Particularly, various strategies to quench QTM effects go hand-in-hand with experiments, and different methods proposed to quell QTM effects are scattered in the literature. In this perspective, we have explored various approaches that are proposed in the literature to quench QTM effects, and these include the role of (i) local symmetry of lanthanides, (ii) super-exchange interaction in {3d-4f} complexes, (iii) direct-exchange interaction in {radical-4f} and metal-metal bonded complexes to suppress the QTM, (iv) utilizing external stimuli such as an electric field or pressure to modulate the QTM and (v) avoiding QTM effects by stabilising toroidal states in 4f and {3d-4f} clusters. We believe the strategies summarized here will help to design new-generation SMMs.