<i>θ</i>-[Mo<sub>8</sub>O<sub>26</sub>]<sup>4−</sup>-based multifunctional hybrid material for high catalytic performance on the cycloaddition of CO<sub>2</sub>, esterification and knoevenagel condensation
Zhengguo Zhang, Hongxiao Lv, Kun Yang, Xiutang Zhang
Abstract
in terms of turnover number and turnover frequency. Moreover, because of open metal sites and rich terminal oxygen atoms, NUC-62 shows high catalytic activity for Knoevenagel condensation reactions of aldehydes and malononitrile. Hence, this study lays the groundwork for constructing heterometallic cluster-based microporous MOFs with excellent Lewis acidic catalysis and chemical stability. Therefore, this study lays a foundation for the construction of functional polyoxometalate complexes.
Topics & Concepts
CatalysisMalononitrileKnoevenagel condensationChemistryCycloadditionLewis acids and basesMicroporous materialLigand (biochemistry)Organic chemistryBiochemistryReceptorMetal-Organic Frameworks: Synthesis and ApplicationsCarbon dioxide utilization in catalysisPolyoxometalates: Synthesis and Applications