Co‐Doping of Al<sup>3+</sup> and Ti<sup>4+</sup> and Electrochemical Properties of LiNiO<sub>2</sub> Cathode Materials for Lithium‐Ion Batteries
Jinmei Wu, Jianwen Yang, Jiawei Zheng, Mengwen Wang, Shengxian Li, Bin Huang, Yanwei Li, Qing Zhu, Quanqi Chen, Shunhua Xiao, Botian Liu
Abstract
Abstract LiNiO 2 cathode material for lithium‐ion batteries has the advantages of high specific capacity, abundant resources, and low cost, but it suffers from difficulties in preparation, structural instability, and serious capacity decay. In this work, highly pure and layered structural LiNi 0.95 Al a Ti 0.05‐ a O 2 ( a =0, 0.025, 0.05) cathode materials were synthesized by a simply sol‐gel method. The cation mixing of Ni 2+ and Li + , structural deterioration, irreversible conversion between H2 and H3 phases and unstable surface and CEI (Cathode‐electrolyte interface) film can be effectively suppressed by co‐doping with Al 3+ and Ti 4+ . A preferred LiNi 0.95 Al 0.025 Ti 0.025 O 2 sample provides a discharge specific capacity of 223 mAh g −1 at 0.1 C and 148.32 mAh g −1 at 5 C, a capacity retention of 72.7 % after 300 cycles at 1 C and a Li + diffusion coefficient of about 2.0×10 −9 cm 2 s −1 .