Litcius/Paper detail

Metal-free semiconductors for visible-light-induced carbocarboxylation of styrenes with aliphatic redox-active esters and CO<sub>2</sub>

Hao Hou, Meizhen Luo, Senmao Zhai, Yuan Tao, Meifang Zheng, Sibo Wang

2023Green Chemistry25 citationsDOIOpen Access PDF

Abstract

A metal-free heterogeneous photoredox system provides a mild, sustainable, and practical route for the carboxyalkylation of olefins using ambient carbon dioxide as a C1 source and aliphatic reactive esters as building blocks.

Topics & Concepts

RedoxChemistryMetalCarbon dioxidePhotochemistryVisible spectrumCarbon fibersSemiconductorActive carbonPhotocatalysisOrganic chemistryInorganic chemistryCatalysisMaterials scienceComposite numberComposite materialEnvironmental protectionOptoelectronicsEnvironmental scienceCarbon dioxide utilization in catalysisCO2 Reduction Techniques and CatalystsRadical Photochemical Reactions