Synthesis of Aliphatic Amides through a Photoredox Catalyzed Radical Carbonylation Involving Organosilicates as Alkyl Radical Precursors
Alex Cartier, Etienne Levernier, Anne‐Lise Dhimane, Takahide Fukuyama, Cyril Ollivier, Ilhyong Ryu, Louis Fensterbank
Abstract
Abstract Alkyl radicals, from primary to tertiary, formed by photocatalyzed oxidation of organosilicates, are involved efficiently in radical carbonylation with carbon monoxide (CO), in the presence of various amines and CCl 4 , leading to a variety of amides in moderate to good yields. magnified image
Topics & Concepts
ChemistryCarbonylationAlkylRadicalPhotoredox catalysisCarbon monoxideCatalysisPrimary (astronomy)Organic chemistryPhotochemistryMedicinal chemistryPhotocatalysisAstronomyPhysicsRadical Photochemical ReactionsSulfur-Based Synthesis TechniquesOxidative Organic Chemistry Reactions