In Situ Phosphorization for Constructing Ni <sub>5</sub> P <sub>2</sub> ‐Ni Heterostructure Derived from Bimetallic MOF for Li–S Batteries
Meng Du, Pengbiao Geng, Wanchang Feng, Haoyang Xu, Bing Li, Huan Pang
Abstract
Abstract Heterostructured materials commonly consist of bifunctions due to the different ingredients. For host material in the sulfur cathode of lithium‐sulfur (Li‐S) batteries, the chemical adsorption and catalytic activity for lithium polysulfides (LiPS) are important. This work obtains a Ni 5 P 2 ‐Ni nanoparticle (Ni 5 P 2 ‐NiNPs) heterostructure through a confined self‐reduction method followed by an in situ phosphorization process using Al/Ni‐MOF as precursors. The Ni 5 P 2 ‐Ni heterostructure not only has strong chemical adsorption, but also can effectively catalyze LiPS conversion. Furthermore, the synthetic route can keep Ni 5 P 2 ‐NiNPs inside of the nanocomposites, which have structural stability, high conductivity, and efficient adsorption/catalysis in LiPS conversion. These advantages make the assembled Li–S battery deliver a reversible specific capacity of 619.7 mAh g − 1 at 0.5 C after 200 cycles. The in situ ultraviolet‐visible technique proves the catalytic effect of Ni 5 P 2 ‐Ni heterostructure on LiPS conversion during the discharge process.