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Halogenation of Li<sub>7</sub>La<sub>3</sub>Zr<sub>2</sub>O<sub>12</sub> solid electrolytes: a combined solid-state NMR, computational and electrochemical study

Bo Dong, Abby R. Haworth, Stephen R. Yeandel, Mark P. Stockham, M. S. James, Jingwei Xiu, Dawei Wang, Pooja Goddard, Karen E. Johnston, Peter R. Slater

2022Journal of Materials Chemistry A20 citationsDOIOpen Access PDF

Abstract

Tetragonal Li 7 La 3 Zr 2 O 12 (LLZO) was halogenated to form cubic LLZOF(Cl) via a low temperature solid state synthetic route using PTFE and PVC polymers.

Topics & Concepts

Solid-stateTetragonal crystal systemSolid solutionSolid-state nuclear magnetic resonanceElectrochemistryElectrolyteMaterials scienceFast ion conductorHalogenationPhysical chemistryCrystallographyInorganic chemistryChemistryCrystal structureNuclear magnetic resonanceOrganic chemistryMetallurgyPhysicsElectrodeAdvanced Battery Materials and TechnologiesAdvancements in Battery MaterialsThermal Expansion and Ionic Conductivity
Halogenation of Li<sub>7</sub>La<sub>3</sub>Zr<sub>2</sub>O<sub>12</sub> solid electrolytes: a combined solid-state NMR, computational and electrochemical study | Litcius