Bimetallic Pd<sup>II</sup> complexes with NHC/Py/PCy<sub>3</sub> donor set ligands: applications in α-arylation, Suzuki–Miyaura and Sonogashira coupling reactions
Adhir Majumder, Rajat Naskar, Shankab J. Phukan, Ramananda Maity
Abstract
Bimetallic Pd II complexes bearing mixed NHC/Py/PCy 3 donor set ligands are presented. A complex with a mixed NHC/PCy 3 donor set ligands shows superior activity compared to the PEPPSI type complexes in α-arylation and Sonogashira coupling reactions.
Topics & Concepts
ChemistrySonogashira couplingBimetallic stripMedicinal chemistryTriphenylphosphinePalladiumCoupling (piping)Combinatorial chemistryCatalysisOrganic chemistryEngineeringMechanical engineeringN-Heterocyclic Carbenes in Organic and Inorganic ChemistryCatalytic Cross-Coupling ReactionsSynthetic Organic Chemistry Methods