Synergistic Lewis acid and Pd active sites of metal–organic frameworks for highly efficient carbonylation of methyl nitrite to dimethyl carbonate
Hanying Wu, Ye‐Yan Qin, Yihong Xiao, Jiangshan Chen, Rong Guo, Siqi Wu, Lei Zhang, Jian Zhang, Yuan‐Gen Yao
Abstract
We for the first time systematically investigated a MOF UiO-66 based catalyst showing the synergistic effect of Lewis acid sites and Pd( ii ) for highly efficient methyl nitrite (MN) carbonylation to dimethyl carbonate (DMC).
Topics & Concepts
CarbonylationDimethyl carbonateNitriteChemistryCarbonateCatalysisLewis acids and basesMetalInorganic chemistryMetal-organic frameworkOrganic chemistryCarbon monoxideNitrateAdsorptionMetal-Organic Frameworks: Synthesis and ApplicationsCarbon dioxide utilization in catalysisCovalent Organic Framework Applications