Mechanochemical synthesis of mixed metal, mixed linker, glass-forming metal–organic frameworks
Michael F. Thorne, María Laura Ríos Gómez, Alice M. Bumstead, Shichun Li, Thomas D. Bennett
Abstract
Methods to produce glass forming metal–organic frameworks (MOFs) rely on solvothermal syntheses which have high energy requirements, low yields and large teratogenic solvent usage. We present mechanochemical methods to overcome these issues.
Topics & Concepts
LinkerMetal-organic frameworkMetalMaterials scienceSolventChemical engineeringNanotechnologyOrganic chemistryChemistryMetallurgyComputer scienceAdsorptionEngineeringOperating systemMetal-Organic Frameworks: Synthesis and ApplicationsCrystallography and molecular interactionsX-ray Diffraction in Crystallography