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Geometric decomposition of entropy production into excess, housekeeping, and coupling parts

Andreas Dechant, Shin-ichi Sasa, Sosuke Ito

2022Physical review. E31 citationsDOIOpen Access PDF

Abstract

For a generic overdamped Langevin dynamics driven out of equilibrium by both time-dependent and nonconservative forces, the entropy production rate can be decomposed into two positive terms, termed excess and housekeeping entropy. However, this decomposition is not unique: There are two distinct decompositions, one due to Hatano and Sasa, the other one due to Maes and Netočný. Here we establish the connection between these two decompositions and provide a simple, geometric interpretation. We show that this leads to a decomposition of the entropy production rate into three positive terms, which we call the excess, housekeeping, and coupling part, respectively. The coupling part characterizes the interplay between the time-dependent and nonconservative forces. We also derive thermodynamic uncertainty relations for the excess and housekeeping entropy in both the Hatano-Sasa and Maes-Netočný decomposition and show that all quantities obey integral fluctuation theorems. We illustrate the decomposition into three terms using a solvable example of a dragged particle in a nonconservative force field.

Topics & Concepts

Entropy productionStatistical physicsEntropy (arrow of time)PhysicsMathematicsThermodynamicsAdvanced Thermodynamics and Statistical MechanicsStatistical Mechanics and Entropystochastic dynamics and bifurcation