Nucleophilic reactivity of the gold atom in a diarylborylgold(<scp>i</scp>) complex toward polar multiple bonds
Akane Suzuki, Xueying Guo, Zhenyang Lin, Makoto Yamashita
Abstract
-hybridized borate species. The DFT calculations also suggested a stepwise mechanism for the reaction of this diarylborylgold complex with isocyanide, which afforded three different reaction products depending on the applied reaction conditions.
Topics & Concepts
Reactivity (psychology)PolarNucleophileChemistryAtom (system on chip)StereochemistryOrganic chemistryCatalysisComputer sciencePhysicsParallel computingMedicineAstronomyAlternative medicinePathologyOrganoboron and organosilicon chemistryMolecular Junctions and NanostructuresSynthesis and characterization of novel inorganic/organometallic compounds