A 1D chiral infinite chain organic metal halide hybrid with excellent SHG switching and moderate spontaneous polarization
Jiachang Zhuang, Yu‐Hui Tan, Xiao‐Wei Fan, Yun‐Zhi Tang, Ning Song, Yihua Zhang, Hao Zhang, Shaopeng Chen
Abstract
A 1D chiral lead-free organic metal halide hybrid C 8 H 20 Cl 5 N 2 O 2 Sb (1) was successfully synthesized. Compound 1 reveals a phase transition and has a SHG “ON–OFF” switchable property, and also have ferroelectric.
Topics & Concepts
ChemistryHalideFerroelectricityPolarization (electrochemistry)MetalMetal halidesPhase transitionTransition metalInorganic chemistryOptoelectronicsOrganic chemistryPhysical chemistryCondensed matter physicsCatalysisDielectricPhysicsPerovskite Materials and ApplicationsSolid-state spectroscopy and crystallographyNonlinear Optical Materials Research