Ketone-functionalized conjugated organic polymers boost red-light-driven molecular oxygen-mediated oxygenation
Hao Zhang, Tingting Yuan, Nursaya Zhumabay, Zhipeng Ruan, Hai Qian, Magnus Rueping
Abstract
as a green oxidant under 640 nm light irradiation, achieving high yield in short reaction times. Detailed mechanistic investigations clearly showed the role of oxygen and the photocatalyst. This work provides valuable insights into the potential of ketone-modified POPs for superior photocatalytic activation of molecular oxygen under low-energy light conditions.
Topics & Concepts
Conjugated systemOxygenationPolymerKetoneMolecular oxygenOxygenChemistryPhotochemistryPolymer chemistryCombinatorial chemistryOrganic chemistryEcologyBiologyRadical Photochemical ReactionsOxidative Organic Chemistry ReactionsLuminescence and Fluorescent Materials