Photocatalytic deracemisation of cobalt(<scp>iii</scp>) complexes with fourfold stereogenicity
Tanno A. Schmidt, Christof Sparr
Abstract
photocatalyst, an enantiomeric enrichment of up to 88 : 12 e.r. was obtained for the major meridional diastereomers. Moreover, a distribution of configurationally stable diastereomers distinct from the thermodynamic ratio was observed upon reaching the photostationary state.
Topics & Concepts
DiastereomerStereocenterCobaltPhotocatalysisEnantiomerPhotostationary stateChemistryZonal and meridionalStereoselectivityMedicinal chemistryStereochemistryOrganic chemistryCatalysisEnantioselective synthesisPhotoisomerizationAtmospheric sciencesIsomerizationGeologyPorphyrin and Phthalocyanine ChemistryMetal-Catalyzed Oxygenation MechanismsOxidative Organic Chemistry Reactions