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Direct Measurements of Isoprene Autoxidation: Pinpointing Atmospheric Oxidation in Tropical Forests

Diogo J. Medeiros, Mark A. Blitz, Paul W. Seakins, Lisa K. Whalley

2022JACS Au26 citationsDOIOpen Access PDF

Abstract

, 5367-5377. In addition, our study indicates that the dihydroperoxide products are significantly enhanced over previous estimates. Dihydroperoxides are chemical and photochemical sources of OH, and the implications of enhanced hydroperoxide formation on the agreement between models and observations in tropical forests are examined.

Topics & Concepts

IsopreneAutoxidationChemistryRadicalPhotochemistryIsomerizationAtmospheric chemistryHydroxyl radicalEnvironmental chemistryOzoneOrganic chemistryPolymerCopolymerCatalysisAtmospheric chemistry and aerosolsPlant responses to elevated CO2Atmospheric Ozone and Climate
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