<scp>LDPE</scp>/<scp>Bi<sub>2</sub>O<sub>3</sub></scp> nanocomposites: Enhanced mechanical, dielectric, and optical properties
Nazlıcan Şahin, Emre Beyazay, Yaşar Karabul, Mehmet Kılıç, Kadir Esmer, Zeynep Güven Özdemir
Abstract
Abstract This study is focused on investigating the role of bismuth oxide (Bi 2 O 3 ) nanoparticles to improve structural, optical, electrical, and mechanical properties of low‐density polyethylene (LDPE). For this purpose, Bi 2 O 3 nanoparticles were synthesized by using the solvothermal method and examined by transmission electron microscopes (TEM), x‐ray diffraction (XRD), Fourier transformed infrared (FTIR) spectroscopy, and ultraviolet–visible (UV–Vis) light absorption methods. LDPE‐based nanocomposites were prepared by changing the nanoparticle additive ratio in the composite from 0% to 2% by weight. The composites were analyzed in the context of their FTIR spectra, atomic force microscope (AFM) images, UV–Vis light absorption spectra, stress–strain curves, and energy storage abilities. While the AFM findings indicate a smoother surface for the composites, the optical band gap analysis reveals a slightly decreased direct optical band gap energy. The analyses based on dielectric spectroscopy also highlight the LDPE/0.5% n‐Bi 2 O 3 composite in terms of the best energy storage capability. Additionally, the highest Young's modulus, toughness, stress at break, and percentage of strain at break were also recorded for the LDPE/0.5% n‐Bi 2 O 3 composite. In this context, the LDPE/0.5% n‐Bi 2 O 3 composite with improved dielectric and mechanical properties can be suggested as a new promising LDPE‐based nanocomposite with better properties for industrial purposes.