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Stepwise assembly of thiacalix[4]arene-protected Ag/Ti bimetallic nanoclusters: accurate identification of catalytic Ag sites in CO<sub>2</sub> electroreduction

Yi-Qi Tian, Wen-Lei Mu, Linlin Wu, Xiao‐Yi Yi, Jun Yan, Chao Liu

2023Chemical Science26 citationsDOIOpen Access PDF

Abstract

Using two structurally closely related Ti/Ag bimetallic clusters as model catalysts, we have for the first time compared CO 2 electroreduction atomic-level activities for different Ag sites on Ag-based catalysts.

Topics & Concepts

Bimetallic stripNanoclustersCatalysisIdentification (biology)Materials scienceNanotechnologyChemistryOrganic chemistryBotanyBiologyNanocluster Synthesis and ApplicationsCO2 Reduction Techniques and CatalystsMetal-Organic Frameworks: Synthesis and Applications
Stepwise assembly of thiacalix[4]arene-protected Ag/Ti bimetallic nanoclusters: accurate identification of catalytic Ag sites in CO<sub>2</sub> electroreduction | Litcius