Thermodynamically stable synthesis of high entropy alloys and efficiently catalyzed oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid under base-free conditions
Guangqiang Lv, Shan Liu, Xiaoyan Chen, Mengxin Chen, Yanjuan Wu, Yu‐Ji Gao, Shuai Wang, Furong Tao, Jingui Wang, Liwei Niu
Abstract
In a completely non-alkaline aqueous system, a high-entropy alloy catalyst composed of FeCoNiCuGaPt activates O 2 and H 2 O molecules to form hydroxyl radicals (˙OH) and efficiently oxidizes 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid.
Topics & Concepts
5-hydroxymethylfurfuralCatalysisAlloyBase (topology)ChemistryEntropy (arrow of time)Organic chemistryThermodynamicsMathematicsPhysicsMathematical analysisCatalytic Processes in Materials ScienceCatalysis and Oxidation ReactionsAdvanced Materials Characterization Techniques