Cationic ring-opening polymerization of a five membered cyclic dithiocarbonate having a tertiary amine moiety
Suvratha Krishnamurthy, Yoshiaki Yoshida, Takeshi Endo
Abstract
A dibenzylamine derived cyclic dithiocarbonate (1) undergoes ring-opening polymerization due to the greater reactivity of exocyclic sulfur compared to the tertiary amine with methyl triflate.
Topics & Concepts
Cationic polymerizationMoietyTertiary amineAmine gas treatingTrifluoromethanesulfonateReactivity (psychology)ChemistryRing (chemistry)PolymerizationPolymer chemistryRing-opening polymerizationSulfurOrganic chemistryCatalysisPolymerAlternative medicinePathologyMedicineSynthesis and properties of polymersAdvanced Polymer Synthesis and CharacterizationAntimicrobial agents and applications