Engineering the HOMO–LUMO gap of indeno[1,2-<i>b</i>]fluorene
Raquel Casares, Álvaro Martínez-Pinel, Sandra Rodríguez‐González, Irene R. Márquez, Luís Lezama, M. Teresa González, Edmund Leary, Víctor Blanco, Joel G. Fallaque, Cristina Dı́az, Fernando Martı́n, Juan M. Cuerva, Alba Millán
Abstract
The insertion of phenyl acetylenes at the reactive positions of indeno[1,2- b ]fluorene leads to tune its optoelectronic and magnetic properties. Furthermore, its single-molecule conductance has been investigated for the first time.
Topics & Concepts
FluoreneHOMO/LUMOMaterials scienceConductanceMoleculeCrystallographyPhotochemistryCondensed matter physicsPolymerOrganic chemistryChemistryPhysicsComposite materialMolecular Junctions and NanostructuresOrganic Electronics and PhotovoltaicsSynthesis and Properties of Aromatic Compounds