Amorphous Manganese Oxides: An Approach for Reversible Aqueous Zinc-Ion Batteries
Yang Wu, Jared Fee, Zachary Tobin, Alireza Shirazi-Amin, Peter Kerns, Shanka Dissanayake, Anne Mirich, Steven L. Suib
Abstract
Crystalline manganese oxides have attracted the most attention in aqueous zinc-ion batteries due to their diverse nanostructures and low cost. However, extensive studies on amorphous manganese oxides are lacking. Here in this paper, we report a mesoporous amorphous manganese oxide (UCT-1-250) as a cathode material with high capacity (222 mAh g<sup>–1</sup>), good cyclability (57% capacity retention after 200 cycles), and an acceptable discharge plateau (between 1.2 and 1.4 V). An approach to mechanistic studies was performed by comparison of UCT-1-250 and other crystalline manganese oxides through electrochemical, elemental, and structural analyses. An in situ conversion to ZnMn<sub>2</sub>O<sub>4</sub> spinel phase after initial cycling contributes to the high performance. The irreversible capacity fading is due to the formation of the woodruffite phase.