Quasi single-crystalline transformation of porous frameworks accompanied by interlayer rearrangements of hydrogen bonds
Haruka Kubo, Ryusei Oketani, Ichiro Hisaki
Abstract
Quasi single-crystal-to-single-crystal transformation of a hydrogen-bonded organic framework (HOF) was accurately revealed and the mechanism was proposed. Interestingly, Br/π interaction allows a snapshot of the intermediate phase of the crystal structure to be solved.
Topics & Concepts
Transformation (genetics)Hydrogen bondSingle crystalMaterials scienceCrystallographyPorosityHydrogenCrystal (programming language)Chemical engineeringPorous mediumChemical physicsChemistryMoleculeComposite materialOrganic chemistryComputer scienceGeneEngineeringProgramming languageBiochemistryMetal-Organic Frameworks: Synthesis and ApplicationsCrystallography and molecular interactionsSupramolecular Self-Assembly in Materials