Recent advances in lithium-rich manganese-based cathodes for high energy density lithium-ion batteries
Hexiang Chen, Chunwen Sun
Abstract
) as well as low cost. However, the problems of fast voltage/capacity fading, poor rate performance and the low initial Coulombic efficiency severely hinder its practical application. In this paper, we review the latest research advances of LRMO cathode materials, including crystal structure, electrochemical reaction mechanism, existing problems and modification strategies. In this review, we pay more attention to recent progress in modification methods, including surface modification, doping, morphology and structure design, binder and electrolyte additives, and integration strategies. It not only includes widely studied strategies such as composition and process optimization, coating, defect engineering, and surface treatment, but also introduces many relatively novel modification methods, such as novel coatings, grain boundary coating, gradient design, single crystal, ion exchange method, solid-state batteries and entropy stabilization strategy. Finally, we summarize the existing problems in the development of LRMO and put forward some perspectives on the further research.