A fluorobenzene-bound dysprosium half-sandwich dication single-molecule magnet
Sophie C. Corner, William J. A. Blackmore, Gemma K. Gransbury, Andrea Mattioni, George F. S. Whitehead, Nicholas F. Chilton, David P. Mills
Abstract
(μ-F)] (4-Y), showing that the fluorobenzenes of 1-Y are easily displaced. We envisage that these methodologies could be adapted in future to prepare high-performance axial Dy SMMs with ligands that are more sterically demanding than Cp*.
Topics & Concepts
FluorobenzeneDysprosiumDicationLanthanideSingle-molecule magnetChemistryMoleculeLigand (biochemistry)MagnetCrystallographyCombinatorial chemistryPhotochemistryInorganic chemistryIonOrganic chemistryPhysicsReceptorBiochemistryQuantum mechanicsBenzeneMagnetic fieldMagnetizationMagnetism in coordination complexesLanthanide and Transition Metal ComplexesPorphyrin and Phthalocyanine Chemistry