Hydrothermal regulation of MnO2 on a wood-based RGO composite for achieving wide voltage windows and high energy density supercapacitors
Xiaofei Shan, Li Wang, Lili Li, Ya Zuo, Zhenghua Fu, Jing Wu, Zhe Wang, Xiaotao Zhang, Ximing Wang
Abstract
The increasing need for improved energy storage devices renders it particularly important that inexpensive electrodes with high capacitance, excellent cycling stability, and environment-friendly characteristics are developed. In this study, a wood-derived carbon@reduced graphene (WRG) conductive precursor with an average conductivity of 15.38 S/m was firstly synthesized. The binder-free WRG-MnO 2 electrode was successfully constructed by growing MnO 2 onto a WRG under hydrothermal conditions. The asymmetric supercapacitor assembled with the WRG- 20 MnO 2 cathode exhibited excellent electrochemical capacitive behavior with a voltage window of 0–2 V, maximum energy density of 52.3 Wh kg −1 , and maximum power density of 1642.7 W kg −1 , which is mainly due to the distinctive icicle-shaped structure of the MnO 2 . Thus, a facile strategy for developing high-performance hierarchical porous carbon electrodes that can be used in supercapacitors was developed herein, which may provide new opportunities to improve the high added value of poplar wood.