Systematic tuning of the emission colors and redox potential of Eu(<scp>ii</scp>)-containing cryptates by changing the N/O ratio of cryptands
Wenchao Yan, Tingzhou Li, Zelun Cai, Hao Qi, Ruoyao Guo, Peihao Huo, Zhiwei Liu, Zuqiang Bian
Abstract
The λ max , excited-state lifetimes, and the anodic peak potential of Eu 2+ /Eu 3+ for Eu( ii )-containing cryptates depend linearly on the number of N atoms.
Topics & Concepts
CryptandExcited stateRedoxChemistryAnodeMolar ratioInorganic chemistryIonPhysical chemistryPhysicsAtomic physicsCatalysisElectrodeOrganic chemistryLanthanide and Transition Metal ComplexesMolecular Sensors and Ion DetectionLuminescence and Fluorescent Materials