Cyclopropylcarbinyl cation chemistry in synthetic method development and natural product synthesis: cyclopropane formation and skeletal rearrangement
Jiaxin Xie, Guangbin Dong
Abstract
In this Review, the underrecognized utilities of the cyclopropylcarbinyl cation chemistry are summarized in cyclopropane synthesis and skeletal rearrangements, and their applications in natural product total synthesis are highlighted.
Topics & Concepts
ChemistryCyclopropaneNatural productCombinatorial chemistryProduct (mathematics)Organic chemistryRing (chemistry)MathematicsGeometryCyclopropane Reaction MechanismsSynthetic Organic Chemistry MethodsAsymmetric Synthesis and Catalysis