Heptagon‐Containing Nanographene Embedded into [10]Cycloparaphenylene
Juan P. Mora‐Fuentes, Marcos D. Codesal, Marco Reale, Carlos M. Cruz, Vicente G. Jiménez, Alice Sciortino, M. Cannas, Fabrizio Messina, Víctor Blanco, Araceli G. Campaña
Abstract
Abstract We report the synthesis and characterization of a novel type of nanohoop, consisting of a cycloparaphenylene derivative incorporating a curved heptagon‐containing π‐extended polycyclic aromatic hydrocarbon (PAH) unit. We demonstrate that this new macrocycle behaves as a supramolecular receptor of curved π‐systems such as fullerenes C 60 and C 70 , with remarkably large binding constants (ca. 10 7 M −1 ), as estimated by fluorescence measurements. Nanosecond and femtosecond spectroscopic analysis show that these host‐guest complexes are capable of quasi‐instantaneous charge separation upon photoexcitation, due to the ultrafast charge transfer from the macrocycle to the complexed fullerene. These results demonstrate saddle‐shaped PAHs with dibenzocycloheptatrienone motifs as structural components for new macrocycles displaying molecular receptor abilities and versatile photochemical responses with promising electron‐donor properties in host‐guest complexes.