Tuning of visible light-driven CO<sub>2</sub>reduction and hydrogen evolution activity by using POSS-modified porous organometallic polymers
Wei-Jia Wang, Kaihong Chen, Zhi‐Wen Yang, Bowen Peng, Liang‐Nian He
Abstract
Introducing polyhedral oligomeric silsesquioxane (POSS) into Re-based porous organometallic polymers (POMPs) successfully optimizes the POMP morphology and electron transfer efficiency, balancing the CO/H<sub>2</sub>molar ratio of the formed syngas.
Topics & Concepts
SilsesquioxanePolymerPorosityMaterials scienceChemical engineeringGroup 2 organometallic chemistryHydrogenPorous mediumPolymer chemistrySyngasChemistryOrganic chemistryMoleculeComposite materialEngineeringCarbon dioxide utilization in catalysisCatalytic Processes in Materials ScienceAdvanced Photocatalysis Techniques