Asymmetric catalytic nitrooxylation and azidation of β-keto amides/esters with hypervalent iodine reagents
Changqiang He, Zhikun Wu, Yuqiao Zhou, Weidi Cao, Xiaoming Feng
Abstract
Chiral Lewis acid-catalyzed enantioselective nitrooxylation and azidation of cyclic and acyclic β-keto amides/esters with hypervalent iodine( iii ) reagents.
Topics & Concepts
Hypervalent moleculeChemistryReagentIodineEnantioselective synthesisCatalysisLewis acids and basesOrganic chemistryCombinatorial chemistryOxidative Organic Chemistry ReactionsSynthesis and Catalytic ReactionsCatalytic C–H Functionalization Methods