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Electrical Characterization of Individual Cesium Lead Halide Perovskite Nanowires Using Conductive AFM

Avigail Stern, Sigalit Aharon, Tal Binyamin, Abeer Karmi, Dvir Rotem, Lioz Etgar, Danny Porath

2020Advanced Materials27 citationsDOI

Abstract

Perovskite nanostructures have attracted much attention in recent years due to their suitability for a variety of applications such as photovoltaics, light-emitting diodes (LEDs), nanometer-size lasing, and more. These uses rely on the conductive properties of these nanostructures. However, electrical characterization of individual, thin perovskite nanowires has not yet been reported. Here, conductive atomic force microscopy characterization of individual cesium lead halide nanowires is presented. Clear differences are observed in the conductivity of nanowires containing only bromide and nanowires containing a mixture of bromide and iodide. The differences are attributed to a higher density of crystalline defects, deeper trap states, and higher inherent conductivity for nanowires with mixed bromide-iodide content.

Topics & Concepts

Materials scienceNanowireHalidePerovskite (structure)Characterization (materials science)IodideNanotechnologyNanostructureElectrical conductorConductivityDiodeNanometreOptoelectronicsChemical engineeringInorganic chemistryComposite materialPhysical chemistryEngineeringChemistryPerovskite Materials and ApplicationsConducting polymers and applicationsQuantum Dots Synthesis And Properties
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