Metal- and photocatalyst-free three-component strategy to prepare benzylalcohol-, aldehyde-substituted BCP building blocks
Fei Li, Huijuan Liao, Jianyang Dong, Weikang Xiong, Y. Yan, Gang Li, Dong Xue
Abstract
A mild one-step, light-promoted, three-component radical-coupling reaction of [1.1.1]propellane to afford difunctionalized benzylalcohol-, aldehyde-substituted BCPs in the absence of metals, photocatalysts or external oxidants was reported.
Topics & Concepts
Component (thermodynamics)PhotocatalysisAldehydeMetalChemistryMaterials scienceNanotechnologyBusinessOrganic chemistryCatalysisPhysicsThermodynamicsSulfur-Based Synthesis TechniquesRadical Photochemical ReactionsChemical Synthesis and Analysis