A long-lived charge-separated state of spiro compact electron donor–acceptor dyads based on rhodamine and naphthalenediimide chromophores
Xiao Xiao, Ivan V. Kurganskii, Partha Maity, Jianzhang Zhao, Xiao Jiang, Omar F. Mohammed, Matvey V. Fedin
Abstract
Spiro compact rhodamine-naphthalenediimide electron donor–acceptor dyads show a long-lived charge separated state (lifetime: 0.72 μs) based on the electron spin control effect were reported.
Topics & Concepts
ChromophoreCharge (physics)AcceptorPhotochemistryElectron acceptorElectron donorChemistryRhodamine BElectronRhodamineFluorescencePhysicsOrganic chemistryOpticsCondensed matter physicsCatalysisPhotocatalysisQuantum mechanicsPorphyrin and Phthalocyanine ChemistryPhotochemistry and Electron Transfer StudiesLuminescence and Fluorescent Materials