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650 ps <scp>SET</scp> speed in <scp>Ge<sub>2</sub>Sb<sub>2</sub>Te<sub>5</sub></scp> phase change memory induced by <scp>TiO<sub>2</sub></scp> dielectric crystal plane

Ruizhe Zhao, Ke Gao, Rong‐Jiang Zhu, Zhuo‐Ran Zhang, Qiang He, Ming Xu, Niannian Yu, Hao Tong, Xiangshui Miao

2024InfoMat14 citationsDOIOpen Access PDF

Abstract

Abstract Crystallization speed of phase change material is one of the main obstacles for the application of phase change memory (PCM) as storage class memory in computing systems, which requires the combination of nonvolatility with ultra‐fast operation speed in nanoseconds. Here, we propose a novel approach to speed up crystallization process of the only commercial phase change chalcogenide Ge 2 Sb 2 Te 5 (GST). By employing TiO 2 as the dielectric layer in phase change device, operation speed of 650 ps has been achieved, which is the fastest among existing representative PCM, and is comparable to the programing speed of commercial dynamic random access memory (DRAM). Because of its octahedral atomic configuration, TiO 2 can provide nucleation interfaces for GST, thus facilitating the crystal growth at the determinate interface area. Ti–O–Ti–O four‐fold rings on the (110) plane of tetragonal TiO 2 is critical for the fast‐atomic rearrangement in the amorphous matrix of GST that enables ultra‐fast operation speed. The significant improvement of operation speed in PCM through incorporating standard dielectric material TiO 2 in DRAM paves the way for the application of phase change memory in high performance cache‐type data storage. image

Topics & Concepts

Phase-change memoryMaterials scienceAmorphous solidDynamic random-access memoryChalcogenideCrystallizationDramNucleationTetragonal crystal systemDielectricPhase (matter)Phase-change materialOptoelectronicsComputer scienceNanotechnologyCrystallographyPhysicsLayer (electronics)Chemical engineeringComputer hardwareChemistryPhase changeEngineeringSemiconductor memoryEngineering physicsQuantum mechanicsThermodynamicsPhase-change materials and chalcogenidesChalcogenide Semiconductor Thin FilmsNonlinear Optical Materials Studies
650 ps <scp>SET</scp> speed in <scp>Ge<sub>2</sub>Sb<sub>2</sub>Te<sub>5</sub></scp> phase change memory induced by <scp>TiO<sub>2</sub></scp> dielectric crystal plane | Litcius