Cyclooctatetraenide-based single-ion magnets featuring bulky cyclopentadienyl ligand
Maciej Damian Korzyński, Moritz Bernhardt, Vladyslav Romankov, Jan Dreiser, Guy Matmon, Fabrice Pointillart, Boris Le Guennic, Olivier Cador, Christophe Copéret
Abstract
Application of steric control principles allows for simplification of the magnetic behavior of an iconic single-ion magnet architecture as well as the preparation of its previously inaccessible representative.
Topics & Concepts
LanthanideSteric effectsCyclopentadienyl complexLigand (biochemistry)Ionic radiusChemistryIonCrystallographyMagnetDerivative (finance)Van de Graaff generatorStereochemistryOrganic chemistryPhysicsFinancial economicsOpticsQuantum mechanicsBiochemistryReceptorBeam (structure)EconomicsCatalysisMagnetism in coordination complexesLanthanide and Transition Metal ComplexesOrganic and Molecular Conductors Research