Reduction of (100)-Faceted CeO<sub>2</sub> for Effective Pt Loading
Akira Yoko, Haodong Wang, Ko Furuya, Daiki Takahashi, Gimyeong Seong, Takaaki Tomai, Anatoly I. Frenkel, Mitsuhiro Saito, Kazutoshi Inoue, Yuichi Ikuhara, Tadafumi Adschiri
Abstract
High Resolution Image Download MS PowerPoint Slide Although the function and stability of catalysts are known to significantly depend on their dispersion state and support interactions, the mechanism of catalyst loading has not yet been elucidated. To address this gap in knowledge, this study elucidates the mechanism of Pt loading based on a detailed investigation of the interaction between Pt species and localized polarons (Ce 3+ ) associated with oxygen vacancies on CeO 2 (100) facets. Furthermore, an effective Pt loading method was proposed for achieving high catalytic activity while maintaining the stability. Enhanced dispersibility and stability of Pt were achieved by controlling the ionic interactions between dissolved Pt species and CeO 2 surface charges via pH adjustment and reduction pretreatment of the CeO 2 support surface. This process resulted in strong interactions between Pt and the CeO 2 support. Consequently, the oxygen-carrier performance was improved for CH 4 chemical looping reforming reactions. This simple interaction-based loading process enhanced the catalytic performance, allowing the efficient use of noble metals with high performance and small loading amounts.