Magnetic materials based on heterometallic Cr<sup>II/III</sup>–Ln<sup>III</sup> complexes
Pooja Shukla, Sourav Das, Prasenjit Bag, Atanu Dey
Abstract
Exchange interaction plays a pivotal role in dictating the single-molecule magnet (SMM) behaviour in heterometallic complexes. This review covers SMM and magnetocaloric effects of Cr( iii )–Ln( iii )-based heterometallic complexes.
Topics & Concepts
Magnetic refrigerationCrystallographyMaterials scienceMoleculeSingle-molecule magnetMagnetChemistryPhysicsMagnetizationMagnetic fieldOrganic chemistryQuantum mechanicsMagnetism in coordination complexesLanthanide and Transition Metal ComplexesPorphyrin and Phthalocyanine Chemistry