Coordinative chain transfer polymerization of 1-decene in the presence of a Ti-based diamine bis(phenolate) catalyst: a sustainable approach to produce low viscosity PAOs
Ahad Hanifpour, Naeimeh Bahri‐Laleh, Mehdi Nekoomanesh, Albert Poater
Abstract
A Ti-based diamine bis(phenolate) catalyst, [Ti{2,2′-(OC<sub>6</sub>H<sub>2</sub>-4,6-<italic>t</italic>Bu<sub>2</sub>)<sub>2</sub>NHMePhMeNH}Cl<sub>2</sub>], was synthesized and fully characterized by elemental analysis and NMR spectroscopy.
Topics & Concepts
CatalysisChemistryDiaminePolymerizationPolymer chemistryViscosityChain transferIntrinsic viscosityOrganic chemistryPolymerRadical polymerizationMaterials scienceComposite materialCarbon dioxide utilization in catalysisbiodegradable polymer synthesis and propertiesAdvanced Polymer Synthesis and Characterization