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Long-Term Autonomic Thermoregulating Fabrics Based on Microencapsulated Phase Change Materials

Paula Félix, Sergiy Minko, В. А. Винокуров, Kirill A. Cherednichenko, Dmitry G. Shchukin

2021ACS Applied Energy Materials53 citationsDOIOpen Access PDF

Abstract

Microcapsules loaded with n-docosane as phase change material (mPCMs) for thermal energy storage with a phase change transition temperature in the range of 36-45 °C have been employed to impregnate cotton fabrics. Fabrics impregnated with 8 wt % of mPCMs provided 11 °C of temperature buffering effect during heating. On the cooling step, impregnated fabrics demonstrated 6 °C temperature increase for over 100 cycles of switching on/off of the heating source. Similar thermoregulating performance was observed for impregnated fabrics stored for 4 years (1500 days) at room temperature. Temperature buffering effect increased to 14 °C during heating cycle and temperature increase effect reached 9 °C during cooling cycle in the aged fabric composites. Both effects remained stable in aged fabrics for more than 100 heating/cooling cycles. Our study demonstrates high potential use of the microencapsulated n-docosane for thermal management applications, including high-technical textiles, footwear materials, and building thermoregulating covers and paints with high potential for commercial applications.

Topics & Concepts

Materials sciencePhase-change materialPhase changeComposite materialAtmospheric temperature rangeThermalRange (aeronautics)Phase (matter)ThermodynamicsChemistryPhysicsOrganic chemistryPhase Change Materials ResearchSolar Thermal and Photovoltaic SystemsAdsorption and Cooling Systems