Switching Hydrogen Bonding to π-Stacking: The Thiophenol Dimer and Trimer
Rizalina Tama Saragi, Marcos Juanes, Cristóbal Pérez, Pablo Pinacho, Denis S. Tikhonov, Walther Camináti, Melanie Schnell, Alberto Lesarri
Abstract
We used jet-cooled broadband rotational spectroscopy to explore the balance between π-stacking and hydrogen-bonding interactions in the self-aggregation of thiophenol. Two different isomers were detected for the thiophenol dimer, revealing dispersion-controlled π-stacked structures anchored by a long S–H···S sulfur hydrogen bond. The weak intermolecular forces allow for noticeable internal dynamics in the dimers, as tunneling splittings are observed for the global minimum. The large-amplitude motion is ascribed to a concerted inversion motion between the two rings, exchanging the roles of the proton donor and acceptor in the thiol groups. The determined torsional barrier of B2 = 250.3 cm–1 is consistent with theoretical predictions (290–502 cm–1) and the monomer barrier of 277.1(3) cm–1. For the thiophenol trimer, a symmetric top structure was assigned in the spectrum. The results highlight the relevance of substituent effects to modulate π-stacking geometries and the role of the sulfur-centered hydrogen bonds.