Synthesis of Reusable CNF/Ag2Se Films as Visible-Light-Driven Photocatalysts for Photocatalytic Degradation of MB
Talaat A. Hameed, Ahmed Salama, Rabab A. Nasr
Abstract
Abstract In our study’s scenario, flexible films were fabricated from TEMPO-oxidized cellulose nanofibers and silver selenide (CNF/Ag 2 Se) as efficient membranes for the degradation of methylene blue (MB). Different concentrations of Ag 2 Se particles were in situ prepared in the presence of CNF. The in-situ synthesis of Ag 2 Se nanoparticles in the presence of CNF was reported as efficient technique for the formation of submicrosize Ag 2 Se particles with a narrow size distribution and homogeneous dispersion onto CNF. TEM analysis revealed that the nanofibers had uniform width and diameter, while XRD demonstrated single-phase orthorhombic β-Ag 2 Se formation. 3D-FESEM showed tiny root measurer values of 28, 30, and 32.56 nm in polymeric films with 2.5, 5, and 10% Ag 2 Se-filled CNF. Polymeric films had visible-driven-light photocatalytic activity because the band gap fell from 4.61 eV (UV area) to 2.71 eV (visible region). The composite’s photocatalytic performance was assessed by MB degradation. 10% of CNF/Ag 2 Se demonstrated maximal photocatalytic activity under simulated sunlight for 60 min, pH 9, and 3 g/L composite weight. The factorial design statistical analysis showed that MB dye photodegradation is mostly affected by irradiation time and dye concentration. Environmental, social, and economic factors are all considered, making this study suitable for implementing photocatalysis to large-scale water treatment systems, which is a key component of sustainability.