The bulky Pd-PEPPSI-embedded conjugated microporous polymer-catalyzed Suzuki–Miyaura cross-coupling of aryl chlorides and arylboronic acids
Chang‐An Wang, Wei Zhao, Yanwei Li, Yinfeng Han, Jianping Zhang, Qun Li, Kun Nie, Jian-Guo Chang, Feng‐Shou Liu
Abstract
A Pd-PEPPSI-IPr embedded conjugated microporous polymer (Pd-PEPPSI-CMP) was shown to be a highly efficient heterogeneous catalyst for the Suzuki–Miyaura-type coupling of aryl chlorides and arylboronic acids.
Topics & Concepts
ArylMicroporous materialChemistryConjugated systemConjugated microporous polymerCatalysisPalladiumPolymer chemistryPolymerOrganic chemistryCombinatorial chemistryAlkylCovalent Organic Framework ApplicationsCatalytic Cross-Coupling ReactionsSulfur-Based Synthesis Techniques