Iron-catalysed 1,2-aryl migration of tertiary azides
Kai‐Jie Wei, Tonghao Yang, Qing Chen, Siyu Liang, Wei Yu
Abstract
1,2-Aryl migration of α,α-diaryl tertiary azides was achieved by using the catalytic system of FeCl2/N-heterocyclic carbene (NHC) SIPr·HCl. The reaction generated aniline products in good yields after one-pot reduction of the migration-resultant imines.
Topics & Concepts
CarbeneArylChemistryCatalysisNitrogenMedicinal chemistryCarbon fibersOrganic chemistryAlkylMaterials scienceComposite materialComposite numberCyclopropane Reaction MechanismsSynthesis and Catalytic ReactionsCatalytic Cross-Coupling Reactions