Litcius/Paper detail

Heterolytic Bond Cleavage in a Scissile Triarylmethane Mechanophore

James R. Hemmer, Chris Rader, Bodo D. Wilts, Christoph Weder, José Augusto Berrocal

2021Journal of the American Chemical Society50 citationsDOI

Abstract

transmittance measurements, we show that this effect is related to scissile cleavage leading to colored triarylmethane carbocations.

Topics & Concepts

HeterolysisChemistryScissile bondBond cleavageHomolysisPhotochemistryCovalent bondCarbocationPolymer chemistryOrganic chemistryRadicalCatalysisActive siteEnzymeForce Microscopy Techniques and ApplicationsMechanical and Optical ResonatorsLipid Membrane Structure and Behavior