Litcius/Paper detail

CO reductive oligomerization by a divalent thulium complex and CO <sub>2</sub> -induced functionalization

Thomas Simler, Karl N. McCabe, Laurent Maron, Grégory Nocton

2022Chemical Science31 citationsDOIOpen Access PDF

Abstract

The divalent thulium complex [Tm(Cp ttt ) 2 ] activates CO to form reductive CO dimerization or trimerization products. These complexes further react with electrophiles, including CO 2 , yielding multicarbon oxygenates and original C–H activation products.

Topics & Concepts

ThuliumDivalentElectrophileChemistrySurface modificationCombinatorial chemistryCatalysisInorganic chemistryOrganic chemistryMaterials sciencePhysical chemistryDopingOptoelectronicsCarbon dioxide utilization in catalysisAsymmetric Hydrogenation and CatalysisCO2 Reduction Techniques and Catalysts