Rotational action spectroscopy of trapped molecular ions

Abstract

, photon-induced dissociation of a chemical bond, a photon-triggered reaction, or photodetachment of an electron. Typically, such experiments are performed on molecular ions, which can be well controlled and mass-selected by guiding and storage techniques. Though coming with many advantages, the application of action schemes to rotational spectroscopy was hampered for a long time by the small energy content of a corresponding photon. Therefore, the first rotational action spectroscopic methods emerged only about one decade ago. Today, there exists a toolbox full of different rotational action spectroscopic schemes which are summarized in this review.

Topics & Concepts