Design and Development of Sustainable Cu<sub>2</sub> (II)- and Mn<sub>2</sub> (III)-Embedded Bifunctional Electrocatalysts: Enhanced Hydrogen and Oxygen Generation
Niteesh Kumar, Lalita Wagh, Sajid Mehmood, Apurba K. Das, Tanmay Kumar Ghorai
Abstract
Nowadays, environmentally friendly, low-cost-effective, and sustainable electrocatalysts used widely for hydrogen and oxygen evolution reactions have come into the limelight as a new research topic for scientists. This study highlights the preparation of two unique and symmetrical dinuclear Cu (II) and Mn (III) bifunctional catalysts by a facile simple slow evaporation and diffusion route. [C 32 H 24 Cu 2 F 4 N 4 O 4 ] (1) and [C 32 H 24 Mn 2 F 4 N 4 O 4 ] (2) both have monoclinic ( C 2/ c (15)) crystal systems, with oxidation states +2 and +3, respectively. Prominent SPR peaks at 372 and 412 nm indicate an M–L charge transfer transition in both complexes. The synthesized electrocatalysts display exceptional catalytic activity for the hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). Complex 1 exhibits enhanced hydrogen generation in 0.5 M H 2 SO 4 with a small overpotential of 216 mV at −10 mA cm –2 along with a significantly lower Tafel value of 97 mV/dec compared to Complex 2 . Moreover, Complex 1 is highly active for the OER in 1 M KOH with a small Tafel slope of 103 mV/dec and a low overpotential of 340 mV to acquire 10 mA cm –2 current density, compared to Complex 2 . Complex 1 and Complex 2 remain stable up to 20 h in acidic electrolyte and up to 36 h and 20 h in the basic electrolyte, respectively.