Enantioselective Synthesis of Five-Membered-Ring Atropisomers with a Chiral Rh(III) Complex
Saad Shaaban, Houhua Li, Felix Otte, Carsten Strohmann, Andrey P. Antonchick, Herbert Waldmann
Abstract
Cp complex for the synthesis of the biaryl atropisomer types that can be accessed from three different five-membered-ring heterocycles.
Topics & Concepts
AtropisomerEnantioselective synthesisChemistryRing (chemistry)StereochemistryCatalysisCombinatorial chemistryOrganic chemistryAxial and Atropisomeric Chirality SynthesisMolecular spectroscopy and chiralityNonlinear Waves and Solitons