Sandwich-Type Heteropolyniobate Templated by Mixed Heteroanions
Zhijie Liang, Yuzan He, Yuanyuan Qiao, Pengtao Ma, Jingyang Niu, Jingping Wang
Abstract
A new organic–inorganic hybrid heteropolyoxoniobate, [{Cu(en)(H2O)4}{Cu(en)2(H2O)}{Cu(en)2(H2O)2}]1.5[H8SiTe8Nb15O64]·6H2O (1; en = ethanediamine), has been successfully synthesized by a conventional method. The compound was directed by pairs of [TeO3]2–/[SiO3]2– ions, generating two novel {TeNb9} and {SiTeNb6} subunits in situ owing to the mixed heteroanion. In addition, the solution behavior of compound 1 was investigated.
Topics & Concepts
ChemistryIonIn situCrystallographyStereochemistryInorganic chemistryOrganic chemistryPolyoxometalates: Synthesis and ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsChemical Synthesis and Reactions